Investigating the influence mechanism of hydrogen partial pressure on fracture toughness and fatigue life by in-situ hydrogen permeation

In this work, we investigate the influence mechanism of hydrogen partial pressure on fracture toughness and fatigue life of a high strength pipeline steel. Both fracture toughness test and fatigue life test are carried out under different hydrogen partial pressure. The experimental results show that with the increasing of hydrogen partial pressure, fracture toughness and fatigue life decrease and the decrease trends gradually flatten out. Hydrogen has a larger effect on fatigue life than fracture toughness. Only 3% hydrogen gas can cause a 67.7% decrease of fatigue life. The in-situ hydrogen permeation test is performed respectively in 2 MPa, 5 MPa and 8 MPa hydrogen partial pressure. With the increasing of hydrogen partial pressure, the increase trend of hydrogen permeation current gradually tends to be gentle, which indicates that the hydrogen atoms entering into the material gradually become saturated. This result can be used to clarify the influence mechanism of hydrogen partial pressure on fracture toughness and fatigue life.     

基于火灾动力学模拟的广府祠堂建筑性能化防火评估

为评估建筑遗产的防火性能,以广东广府地区典型祠堂建筑——广州陈氏书院为例,采用火灾动力学模拟(FDS)软件PyroSim计算其中厅堂建筑的火灾烟气流动与热量传递,进而评估山墙和青云巷等传统防火构造性能.结果 表明:传统坡屋顶下火灾烟气沿水平方向流动速度比沿垂直方向更快,容易在山墙部位形成高温,以致烧穿屋顶;山墙和青云巷可使相邻建筑外墙入射热通量降低约3/4;火灾蔓延除与山墙垂脊高度和青云巷宽度相关外,还取决于风速.因此,祠堂类高大厅堂建筑室内应设置纵向挡烟垂壁与自然排烟天窗,控制初始火场面积,减少火灾危害;当环境风速大于4m/s时,祠堂建筑应警惕屋顶飞火的远距离引燃风险,避免风环境恶化是建筑遗产防火保护的一项重要内容.     

Synthetic copolymer (AM/AMPS/DMDAAC/SSS) as rheology modifier and fluid loss additive at HTHP for water-based drilling fluids

In the petroleum industry, high temperature and high pressure (HTHP) would dramatically worsen rheological properties and increase fluid loss volumes of drilling fluids. Synthetic polymer as an indispensable additive has attracted more and more attention recently. In this article, a new copolymer (named AADS) of 2-acrylamide-2-methylpropanesulfonic acid, acrylamide, dimethyl diallyl ammonium chloride, and sodium styrene sulfonate was synthesized through aqueous solution polymerization. The chemical structure of the copolymer was characterized by Fourier transform infrared spectroscopy and nuclear magnetic resonance. Moreover, its thermal stability was simultaneously analyzed using a differential scanning calorimetry. The results showed that the synthetic polymer contained all the designed functional groups, and its structure was consistent to the desired one. Under contamination of sodium chloride, AADS solution maintained relatively high viscosity in high concentration brine, showing a good antisalt capacity. Furthermore, the effect of AADS content and temperature on rheological behavior and fluid loss volume of the water-based drilling fluid (WBDF) containing the synthesized product were investigated according to the American Petroleum Institute standard. Results showed that the rheological and filtration properties of the prepared WBDF were improved with the increase in the AADS concentration before and after the thermal aging test. In addition, in the temperature range of 80–240 °C, a reversible rheological behavior was observed during the heating–cooling process, and the HTHP fluid loss was controlled within 22.5 mL, suggesting that the copolymer AADS was suitable for making WBDF s with high temperature resistance. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47813.     

多氢酸酸化反应特征及动力学

利用自制多氢酸液XS-1进行静态岩粉溶蚀与岩心流动实验,通过SEM、ICP等实验考察了多氢酸的缓速性与预防二次沉淀性能,并研究了多氢酸与岩心反应动力学特性。结果表明,XS-1多氢酸液具有良好的缓速与预防二次沉淀性能,反应后残酸的极限浓度为0.296 1 mol/L,酸液有效作用时间为6~7 h。在该多氢酸体系下岩心渗透率提高至4.15倍,在此条件下以酸岩反应动力学参数模型建立动力学方程,反应速率比同条件下普通酸液小,进一步证明多氢酸具有一定的缓速性。     

Effects of the biaxial orientation on the mechanical and optical properties and shrinkage of polyamide 6-66–montmorillonite–nanosilica nanocomposite films

Polyamide 6–66 (PA6-66)–montmorillonite (MMT)–nanosilica (NS) nanocomposite films were fabricated through a cast film process and then biaxially stretched on a laboratory stretcher. Uniaxial or biaxial stretching induced the elongated conformation of MMT and NS. The b axis of the α crystals and the amorphous phase were revealed to align along the machine direction (MD) after stretching, with the uniaxial orientation playing a more significant role. Furthermore, the crystallinity of PA6-66 stretching increased with the stretching ratio. Uniaxial stretching gave rise to a significantly enhanced tensile strength along the MD, whereas it slightly decreased the mechanical properties along the transverse direction (TD). In contrast, the films subjected to biaxial stretching exhibited more balanced mechanical properties. Uniaxial and biaxial stretching led to decreased transmittance and increased haze in the PA6-66–MMT–NS films; this could have been due to the elongated nanostructure of the two nanofillers, which inhibited the transmission and facilitated the scattering of visible light. The thermal shrinkage of the films increased with increasing stretching ratio, and the biaxially oriented films presented nearly equal shrinkage in the MD and TD. The addition of nanofillers decreased the shrinkage attributed to the mobility inhibition of the polymer chains during heating. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47504.     

Thermal and pH dual‐responsive hydrogels based on semi‐interpenetrating network of poly(N‐isopropylacrylamide) and collagen nanofibrils

Hydrogels with environment‐sensitive properties have great potential applications in the controlled drug release field. In this paper, hybrid hydrogels with semi‐interpenetrating polymer networks (semi‐IPNs), composed of poly(N‐isopropylacrylamide) (PNIPAM) as the thermo‐sensitive component by in situ polymerization and self‐assembled collagen nanofibrils as the pH‐sensitive framework, were prepared for controlled release of methyl violet as a model drug. From Fourier transform infrared spectroscopy and scanning electron microscopy, it was indicated that the crosslinking of PNIPAM in the presence of collagen nanofibrils led to the formation of semi‐IPNs with homogeneous porous structure, and the semi‐IPNs showed improved thermal stability and elastic properties compared with the native collagen as determined using differential scanning calorimetry and rheologic measurements. Furthermore, the semi‐IPNs possessed swelling behaviors quite different from those of neat collagen or PNIPAM hydrogel under various pH values and temperatures. Correspondingly, as expected, the drug release behavior in vitro for semi‐IPNs performed variously compared with that for single‐component semi‐IPNs, which revealed the tunable performance of semi‐IPNs for release ability. Finally the thermo‐ and pH‐responsive mechanism of the semi‐IPNs was illuminated to provide guidance for the application of the thermo‐ and pH‐sensitive collagen‐based hybrid hydrogels in controlled drug delivery systems. © 2019 Society of Chemical Industry     

Lead-free sodium niobate nanowires with strong piezo-catalysis for dye wastewater degradation

In this work, the hydrothermally-synthesized sodium niobate nanowires were used to decompose Rhodamine B dye solution through the piezo-catalytic effect. With the sodium niobate catalyst, a high piezo-catalytic degradation ratio of ～80% was achieved under the excitation of vibration for the Rhodamine B dye solution (～5?mg/l). These active species in the catalytic process, hydroxyl radicals and superoxide radicals with the strong oxidation ability, were also observed, which confirmed the key role of piezoelectric effect for piezo-catalysis. The piezo-catalysis of sodium niobate nanowires provides a high-efficiency and reusable tool in application in depredating the dye wastewater.     

流量替代渗透率评价破碎性储层工作流体伤害程度

若地层岩石整体强度偏低,在力学环境改变后岩石易破碎成不规则破裂体,则储存油气资源的此类破碎地层被称为破碎性储层。由于破碎性储层在纵向上存在着较强的非均质性,通过测试单个柱塞岩样在工作流体伤害前后的渗透率变化难以体现工作流体对储层的整体伤害程度。为此,利用达西定律先从理论上探讨用流量替代渗透率定量表征储层伤害程度的可行性,再开展单层开采、双层及三层并采的流量测试实验,评价工作流体对单层、多层储层的整体伤害程度,并将流量损害率与渗透率损害率进行对比以求证流量替代渗透率的可行性。研究结果表明:①单层开采时,流量损害率与渗透率损害率基本一致,渗透率损害率是流量损害率的一种特殊形式;②双层及三层并采时,单层各自稳定流量损害率与渗透率损害率接近,且流量损害率可以定量表征并采储层的整体伤害程度,而渗透率损害率则无法定量表证;③稳定流量损害率较累积流量损害率更接近渗透率损害率。结论认为,测定稳定流量可以替代测定渗透率评价工作流体对破碎性储层的伤害程度,从而为优选工程技术与评价工作流体的适应性提供了方法依据。     

Docker容器化下的遥感算法程序集成方法

目的 近年来，随着我国遥感技术的快速发展，遥感数据呈现出大数据的特点，遥感数据的时效性增强，针对新环境下遥感算法编程语言众多，程序运行和部署环境需求多样，程序的集成和部署困难的问题，提出了一种遥感算法程序快速封装与Docker容器化系统集成架构。方法 该系统架构主要包括：1）遥感算法程序的镜像自动化封装制作；2）镜像的分发管理，达到算法程序镜像的共享；3）遥感信息产品生产流程的容器化编排服务，将相关联的算法程序镜像串联，以满足特定遥感信息产品的生产；4）容器的调度运行，调用镜像，实现特定遥感产品的容器化运行。本文在上述容器化系统集成架构下，以Landsat5数据的NDVI、NDWI信息产品的生产作为容器化生产实例，并同物理机、KVM （kernel-based virtual machine）虚拟机在运行时间、内存占用量、部署效率等性能进行了对比。结果 Docker容器虚拟化环境下的产品生产和物理机环境下在运行时间和内存占用量上几无差别，优于KVM虚拟机。Docker容器虚拟化环境和KVM虚拟机环境下在部署上能够节省大量时间，相比于物理机环境能够提高部署效率。结论 容器化的系统集成方式能够有效解决遥感算法程序集成和部署困难的问题，有利于遥感算法程序的复用和流程的共享，提高系统集成效率，具备较强的遥感数据实时快速处理能力。